Potassium-mediated zincation of ferrocene and ruthenocene: potassium, the architect behind supramolecular structural variations.
نویسندگان
چکیده
Direct zincation of ferrocene and ruthenocene by the synergic base [PMDETA x K(mu-TMP)(mu-Me)Zn(Me)] produces the monozincated complexes [{PMDETA x K(mu-Me)(2)Zn(Fc)}(infinity)] and [{PMDETA x K(mu-Me)(2)Zn(Rc)}(2)], respectively, having similar monomeric (dinuclear) units but aggregating supramolecularly in very different polymeric and dimeric forms.
منابع مشابه
A Comparative study of Ferrocene and Ruthenocene Complexes
Ferrocene and Ruthenocene are dicyclopentadienyl complexes, where the metal (Fe and Ru) is sandwiched between two cyclopentadienyl structures. The paper describes a comparative study of the electronic and geometric structural properties of ferrocene and ruthenocene. The various physical properties (stability, geometry, symmetry etc.) of the two are reviewed to elucidate the differences between ...
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ورودعنوان ژورنال:
- Dalton transactions
دوره 1 شماره
صفحات -
تاریخ انتشار 2010